Big Oxy-Acet rig for anything over 2". Forget the little bottles of Mapp and propane gas with small torch heads, it won't get the copper hot enough.
Using a large tip with an oxy/acet tank, heat all sides of the line evenly....heat one side of the line, then direct the flame on the other, so that the solder flows evenly into the joint and you don't have any cold spots. I always use No-Korrode flux. Plain 95-5 solder or as Stubby says Silver Solder for other applications or for buried lines.
The tank and tips you'll need are'nt cheap, so before you buy one figure out whether it will be cost effective for you to own one (doing more than just one 2"++ sweat job).
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D.M.
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