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My experience is rather minimal as I've only been using my finish nailer for a little over a year. However, I've never seen "brass" listed in any nailer supplies. I would think it would be too soft for such use. There are galvanized nails for outdoor use, and perhaps even a few other platings, but I've never seen brass.
I see steel, galvanized and stainless steel but no brass. I agree with CWSmith that brass would be too soft. You can get brass hand nails if your using them for decorative purposes. You would probably want to pre-drill especially if going into hardwood.